Mobile phase effects in Rh/sulfonated phosphine/molten salts catalysed the biphasic hydroformylation of heavy olefins

被引：73

作者：

Dupont, J ^{[1
]}

Silva, SM ^{[1
]}

de Souza, RF ^{[1
]}

机构：

[1] Univ Fed Rio Grande do Sul, Inst Quim, Lab Mol Catalysis, BR-91501970 Porto Alegre, RS, Brazil

来源：

CATALYSIS LETTERS | 2001年 / 77卷 / 1-3期

关键词：

hydroformylation; ionic liquids; molten salts; rhodium; biphasic catalysis;

D O I：

10.1023/A:1012778826542

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rh(acetylacetonate)(CO)(2)/sulfonated-Xantphos dissolved in pure 1-n-butyl-3-methylimidazolium hexafluorophosphate ionic liquid catalyses the hydroformylation of heavy olefins (C-8-C-12) with selectivities (up to 99% in n-aldehydes). The selectivity is strongly influenced by the nature of the ionic phase and co-solvent.

引用

页码：131 / 133

页数：3

共 5 条

[1] Mobile Phase Effects in Rh/Sulfonated Phosphine/Molten Salts Catalysed the Biphasic Hydroformylation of Heavy Olefins
Jairton Dupont
Silvana M. Silva
Roberto F. de Souza
Catalysis Letters, 2001, 77 : 131 - 133
[2] A novel thermoregulated phosphine ligand used for the Rh-catalyzed hydroformylation of mixed C11-12 olefins in aqueous/organic biphasic system
Ji, Zhi Jiang
Jiang, Jing Yang
Wang, Yan Hua
CHINESE CHEMICAL LETTERS, 2010, 21 (05) : 515 - 518
[3] A novel thermoregulated phosphine ligand used for the Rh-catalyzed hydroformylation of mixed C11-12 olefins in aqueous/organic biphasic system
Zhi Jiang Ji
Chinese Chemical Letters, 2010, 21 (05) : 515 - 518
[4] Kinetic and Mechanisms of the Aqueous-Biphasic Hydroformylation of Olefins Contained in Naphtha Cuts Catalyzed by RhH(CO)(TPPTS)3 [TPPTS: Tri(sodium m-sulfonated-phenyl)phosphine]
P. J. Baricelli
María Modroño Alonso
Merlín Rosales
Catalysis Letters, 2018, 148 : 1150 - 1161
[5] Kinetic and Mechanisms of the Aqueous-Biphasic Hydroformylation of Olefins Contained in Naphtha Cuts Catalyzed by RhH(CO)(TPPTS)3 [TPPTS: Tri(sodium m-sulfonated-phenyl)phosphine]
Baricelli, P. J.
Modrono Alonso, Maria
Rosales, Merlin
CATALYSIS LETTERS, 2018, 148 (04) : 1150 - 1161

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