Hypervalent Iodine-Mediated Synthesis of Spiroheterocycles via Oxidative Cyclization

被引：17
|
作者：
Xing, Linlin [1 ]
Zhang, Yong [1 ]
Du, Yunfei [1 ,2 ]
机构：
[1] Tianjin Univ, Sch Pharmaceut Sci & Technol, Tianjin Key Lab Modern Drug Delivery & High Effic, Tianjin 300072, Peoples R China
[2] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China
来源：
CURRENT ORGANIC CHEMISTRY | 2019年 / 23卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Hypervalent iodine reagents; spiroheterocycles; oxidative cyclization; metal-free conditions; dearomatization; cascade annulation; CARBON BOND FORMATION; PHENOL DEAROMATIZATION; SPIRO HETEROCYCLES; FACILE CONSTRUCTION; CASCADE ANNULATION; C-O; DERIVATIVES; REAGENT; SPIROCYCLIZATION; INDOLE;
D O I：
10.2174/1385272822666181211122802
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Hypervalent iodine reagents have been widely used in the construction of many important building blocks and privileged scaffolds of bioactive natural products. This review article aims to briefly discuss strategies that have used hypervalent iodine reagents as oxidants to synthesize spiroheterocyclic compounds and to stimulate further study for novel syntheses of spiroheterocyclic core structures using hypervalent iodine reagents under metal-free conditions.
引用
收藏
页码：14 / 37
页数：24
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