Structure-directing role of immobilized polyoxometalates in the synthesis of porphyrinic Zr-based metal-organic frameworks

被引：15

作者：

Duguet, Mathis ^{[1
,2
]}

Lemarchand, Alex ^{[2
]}

Benseghir, Youven ^{[1
,2
]}

Mialane, Pierre ^{[1
]}

Gomez-Mingot, Maria ^{[2
]}

Roch-Marchal, Catherine ^{[1
]}

Haouas, Mohamed ^{[1
]}

Fontecave, Marc ^{[2
]}

Mellot-Draznieks, Caroline ^{[2
]}

Sassoye, Capucine ^{[3
]}

Dolbecq, Anne ^{[1
]}

机构：

[1] Univ Paris Saclay, UVSQ, CNRS, UMR 8180,Inst Lavoisier Versailles, F-78035 Versailles, France

[2] Sorbonne Univ, Lab Chim Proc Biol, UMR CNRS 8229, Coll France,PSL Res Univ, 11 Pl Marcelin Berthelot, F-75231 Paris 05, France

[3] Sorbonne Univ, UMR 7574, Coll France, Lab Chim Matiere Condensie Paris, 4 Pl Jussieu, F-75252 Paris 05, France

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 70期

关键词：

DIFFRACTION;

D O I：

10.1039/d0cc04283h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We evidence the structure-directing role of the PW(12)O(40)(3-)polyoxometalate in porphyrinic MOF synthesis whereby it promotes the formation of the kinetic topology. Its immobilization into the MOF is successfully achieved at a high temperature yielding the kinetic MOF-525/PCN-224 phases, while prohibiting the formation of the thermodynamic MOF-545 product. A combined experimental/theoretical approach uses differential PDF and DFT calculations along with solid-state NMR to show the structural integrity of the POM and its location next to the Zr-based nodes.

引用

下载

页码：10143 / 10146

页数：4

共 50 条

[1] Zr-based metal-organic frameworks: design, synthesis, structure, and applications
Bai, Yan
Dou, Yibo
Xie, Lin-Hua
Rutledge, William
Li, Jian-Rong
Zhou, Hong-Cai
CHEMICAL SOCIETY REVIEWS, 2016, 45 (08) : 2327 - 2367
[2] Structure-directing effects of ionic liquids in the ionothermal synthesis of metal-organic frameworks
Vaid, Thomas P.
Kelley, Steven P.
Rogers, Robin D.
IUCRJ, 2017, 4 : 380 - 392
[3] Structure-Directing Role of Graphene in the Synthesis of Metal-Organic Framework Nanowire
Jahan, Maryam
Bao, Qiaoliang
Yang, Jia-Xiang
Loh, Klan Ping
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (41) : 14487 - 14495
[4] Microwave-assisted synthesis of Zr-based metal-organic frameworks and metal-organic cages
Jiang, Bao-Xu
Wang, Hui
Zhang, Yu-Teng
Li, Shuang-Bao
POLYHEDRON, 2023, 243
[5] Zr-Based Metal-Organic Frameworks for Green Biodiesel Synthesis: A Minireview
Zhang, Qiuyun
Wang, Jialu
Zhang, Shuya
Ma, Juan
Cheng, Jingsong
Zhang, Yutao
BIOENGINEERING-BASEL, 2022, 9 (11):
[6] Dry-Gel Conversion Synthesis of Zr-Based Metal-Organic Frameworks
Lu, Ningyue
Zhou, Fan
Jia, Huanhuan
Wang, Hongyan
Fan, Binbin
Li, Ruifeng
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2017, 56 (48) : 14155 - 14163
[7] Sorption studies on isorecticular Zr-based metal-organic frameworks
Wang, Xuan
Chen, Yinpin
Zhou, Hongcai
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
[8] Role of Zr6 Metal Nodes in Zr-Based Metal-Organic Frameworks for Catalytic Detoxification of Pesticides
Nam, Dongsik
Kim, Yeongjin
Kim, Miyeon
Nam, Joohan
Kim, Seonghoon
Jin, Eunji
Lee, Chang Yeon
Choe, Wonyoung
INORGANIC CHEMISTRY, 2021, 60 (14) : 10249 - 10256
[9] Structure-directing factors when introducing hydrogen bond functionality to metal-organic frameworks
Forgan, Ross S.
Marshall, Ross J.
Struckmann, Mona
Bleine, Aurore B.
Long, De-Liang
Bernini, Maria C.
Fairen-Jimenez, David
CRYSTENGCOMM, 2015, 17 (02): : 299 - 306
[10] Unveiling the mechanism of the photocatalytic reduction of CO2 to formate promoted by porphyrinic Zr-based metal-organic frameworks
Benseghir, Youven
Sole-Daura, Albert
Cairnie, Daniel R.
Robinson, Amanda L.
Duguet, Mathis
Mialane, Pierre
Gairola, Priyanka
Gomez-Mingot, Maria
Fontecave, Marc
Iovan, Diana
Bonnett, Brittany
Morris, Amanda J.
Dolbecq, Anne
Mellot-Draznieks, Caroline
JOURNAL OF MATERIALS CHEMISTRY A, 2022, 10 (35) : 18103 - 18115

← 1 2 3 4 5 →