ATRP of methyl methacrylate in the presence of ionic liquids with ferrous and cuprous anions

被引：5
|
作者：
Sarbu, T [1 ]
Matyjaszewski, K [1 ]
机构：
[1] Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA
来源：
MACROMOLECULAR CHEMISTRY AND PHYSICS | 2001年 / 202卷 / 17期
关键词：
atom transfer radical polymerization (ATRP); chloroaluminate; controlled radical polymerization; copper halide; copper mediated living radical polymerization; imidazolium salts; ionic liquids; iron halide; iron mediated living radical polymerization; methyl methacrylate;
D O I：
10.1002/1521-3935(20011101)202:17<3379::AID-MACP3379>3.0.CO;2-3
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) was studied in the presence of ionic liquids possessing a range of counterions. Iron mediated ATRP can be carried out in the absence of added organic ligands in the presence of ionic liquids. However, copper mediated ATRP of MMA requires the presence of an added organic ligand when the ionic liquid has a halide or a carbonate anion, but not with a phosphonate anion. The ionic liquids containing transition metal salts can readily be separated from the polymerization media and regeneration of the catalyst in the ionic liquids has been successful.
引用
收藏
页码：3379 / 3391
页数：13
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