Lewis Base Catalyzed Nucleophilic Substitutions of Alcohols

被引：38
|
作者：
Huy, Peter H. [1 ]
Hauch, Tanja [1 ]
Filbrich, Isabel [1 ]
机构：
[1] Univ Saarland, Inst Organ Chem, POB 151150, D-66041 Saarbrucken, Germany
来源：
SYNLETT | 2016年 / 27卷 / 19期
关键词：
homogenous catalysis; nucleophilic substitution; halogenation; organocatalysis; Lewis base catalysis; green chemistry; sustainability; GREEN CHEMISTRY; MITSUNOBU REACTIONS; ALKYL CHLORIDES; CONVERSION; HALIDES; CHLORINATION; REPLACEMENT; ACTIVATION; PHOSPHINE; REAGENTS;
D O I：
10.1055/s-0036-1588633
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Nucleophilic substitutions (S-N) at sp(3)-hybridized carbon centers are one of the most fundamental type of transformation in organic synthesis. Taking the importance of bimolecular S-N reactions into account, catalytic variants must be considered as underdeveloped. This review highlights the most recent progress in the emerging field of Lewis base catalyzed S-N-type transformations that are mediated by simple acid chlorides and anhydrides. 1 Introduction 2 Phosphine Oxide and Cyclopropenone Catalysis 3 Formamide Catalysis 4 Other Catalytic Systems 5 Conclusion
引用
收藏
页码：2631 / 2636
页数：6
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