Low thermal-conductivity and high thermal stable silica aerogel based on MTMS/Water-glass co-precursor prepared by freeze drying

被引:107
|
作者
Pan, Yuelei [1 ]
He, Song [1 ]
Gong, Lunlun [1 ]
Cheng, Xudong [1 ]
Li, Congcong [1 ]
Li, Zhi [1 ]
Liu, Zhong [2 ]
Zhang, Heping [1 ]
机构
[1] Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230027, Anhui, Peoples R China
[2] ECONANO Beijing Tech Ltd, Beijing 100176, Peoples R China
关键词
Silica aerogels; MTMS/Water-glass; Freeze drying; Hydrophobic; Thermal stability; SURFACE CHEMICAL-MODIFICATION; PHYSICAL-PROPERTIES; LOW-DENSITY; XEROGELS;
D O I
10.1016/j.matdes.2016.09.083
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this paper, hybrid silica aerogels were prepared by methltrimethoxysilane (MTMS) and water-glass co-precursor through two-step sol-gel process followed by freeze drying (FD). The characteristics of aerogels were strongly affected by the molar ratio of MTMS/Water-glass. When the molar ratio is 5.1, hybrid aerogel was obtained with good performances, such as low density (0.083 g/cm(3)), high contact angle (155.1 degrees) and low thermal conductivity (0.0226 W/m.K). The density, contact angle and thermal conductivity of aerogels based on co-precursor are still showing excellent thermal stability with the same performances after 550 degrees C heat-treatment. (C) 2016 Published by Elsevier Ltd.
引用
收藏
页码:246 / 253
页数:8
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