Oxido-peroxido molybdenum(VI) complexes in catalytic and stoichiometric oxidations

被引：115
|
作者：
Amini, Mojtaba [1 ]
Haghdoost, Mohammad Mehdi [2 ]
Bagherzadeh, Mojtaba [2 ]
机构：
[1] Univ Maragheh, Fac Sci, Dept Chem, Maragheh, Iran
[2] Sharif Univ Technol, Dept Chem, Tehran, Iran
来源：
COORDINATION CHEMISTRY REVIEWS | 2013年 / 257卷 / 7-8期
关键词：
Oxido-peroxido; Molybdenum(VI); Epoxidation; Oxidation; Catalyst; OLEFIN EPOXIDATION CATALYSTS; MESOPOROUS MCM-41 MATERIALS; UREA HYDROGEN-PEROXIDE; X-RAY-STRUCTURE; METAL CATALYSIS; OXYGEN-TRANSFER; PEROXOMOLYBDENUM COMPLEXES; OXOPEROXO MOLYBDENUM(VI); ALKYL HYDROPEROXIDES; CRYSTAL-STRUCTURE;
D O I：
10.1016/j.ccr.2012.11.018
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This review mainly discusses the application of oxido-peroxido Molybdenum(VI) complexes as catalysts or mediators in homogeneous or heterogeneous catalytic systems for oxidations of olefins, sulfides, alcohols, alkanes, and amines toward the synthesis of a variety of organic compounds, such as epoxides, sulfoxides, aldehydes and ketones, carboxylic acids, alcohols and nitroso compounds. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：1093 / 1121
页数：29
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