Proton-Conducting Polymer Electrolyte Membranes: Water and Structure in Charge

被引：54
|
作者：
Eikerling, Michael [1 ,2 ]
Kornyshev, Alexei A. [3 ]
Spohr, Eckhard [4 ,5 ]
机构：
[1] Simon Fraser Univ, Dept Chem, Burnaby, BC V5A 1S6, Canada
[2] CNR, Inst Fuel Cell Innovat, Vancouver, BC V6T 1W5, Canada
[3] Univ London Imperial Coll Sci Technol & Med, Fac Phys Sci, Dept Chem, London SW7 2AZ, England
[4] Univ Duisburg Essen, Lehrstuhl Theoret Chem, D-45141 Essen, Germany
[5] Forschungszentrum Julich, Inst Energieforsch Brennstoffzellen 3, D-52425 Julich, Germany
来源：
FUEL CELLS I | 2008年 / 215卷
关键词：
Atomistic simulations; Fuel cells; Ionomer membranes; Network models and theory; Pore morphology and proton conductance; Proton transfer;
D O I：
10.1007/12_2008_132
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
This article reviews the structure and properties of aqueous-based proton-conducting membranes for fuel cell applications. We will discuss (1) structure of and phase separation in the membranes, (2) principles of proton mobility in hydrogen-bonded aqueous networks, (3) proton conductance through the percolating aqueous phase inside the membrane, and (4) the effects determining membrane performance in a fuel cell.
引用
收藏
页码：15 / 54
页数：40
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