Chromium catalyzed oxidation of (homo-)allylic and (homo-)propargylic alcohols with sodium periodate to ketones or carboxylic acids

被引：0
|
作者：
Schmieder-van de Vondervoort, L
Bouttemy, S
Padrón, JM
Le Bras, J
Muzart, J
Alsters, PL
机构：
[1] DSM Fine Chem Adv Synth & Catalysis, NL-6160 MD Geleen, Netherlands
[2] Univ Reims, CNRS, Unite Mixte Rech React Select & Applicat, F-51687 Reims 2, France
来源：
SYNLETT | 2002年 / 02期
关键词：
alcohols; catalysis; oxidations; sodium periodate; sodium dichromate;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Primary and secondary (homo-)allylic and (homo-)propargylic alcohols can be oxidized under slightly acidic conditions at or below room-temperature with sodium periodate in the presence of sodium dichromate as the catalyst to the corresponding carboxylic acids and ketones, respectively.
引用
收藏
页码：243 / 246
页数：4
相关论文
共 25 条
  • [1] Cr catalyzed oxidation of (homo-)allylic and (homo-)propargylic alcohols with sodium periodate.
    Alsters, P
    Schmieder, L
    Muzart, J
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U166 - U166
  • [2] Palladium-catalyzed isomerization of (homo-)allylic alcohols in molten tetrabutylammonium bromide, a recyclable system
    Ganchegui, B
    Bouquillon, S
    Hénin, F
    Muzart, J
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 214 (01) : 65 - 69
  • [3] STEPHENS-CASTRO-COUPLING OF HALOGENATED VINYLIC AND ALLYLIC SILANES WITH (HOMO-)PROPARGYLIC COMPOUNDS
    KABBARA, J
    HOFFMANN, C
    SCHINZER, D
    [J]. SYNTHESIS-STUTTGART, 1995, (03): : 299 - 302
  • [4] A Rh(I)-catalyzed cycloisomerization of homo- and bis-homopropargylic alcohols
    Trost, BM
    Rhee, YH
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (25) : 7482 - 7483
  • [5] Homo- and heteroleptic cobalt(II) and nickel(II) complexes with nitrilotriacetic and dibasic carboxylic acids
    Kornev, V. I.
    Semenova, M. G.
    Merkulov, D. A.
    [J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2009, 35 (07) : 519 - 525
  • [6] Homo- and heteroleptic cobalt(II) and nickel(II) complexes with nitrilotriacetic and dibasic carboxylic acids
    V. I. Kornev
    M. G. Semenova
    D. A. Merkulov
    [J]. Russian Journal of Coordination Chemistry, 2009, 35 : 519 - 525
  • [7] Synthesis of Biaryls by Pd-Catalyzed Decarboxylative Homo- and Heterocoupling of Substituted Benzoic Acids
    Xie, Kai
    Wang, Sizhuo
    Yang, Zhiyong
    Liu, Jidan
    Wang, Anwei
    Li, Xiujian
    Tan, Ze
    Guo, Can-Cheng
    Deng, Wei
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2011, 2011 (29) : 5787 - 5790
  • [8] Nickel-Catalyzed Homo- and Cross-Coupling of Allyl Alcohols via Allyl Boronates
    Gan, Yi
    Hu, Hui
    Liu, Zhaohong
    [J]. ORGANIC LETTERS, 2020, 22 (11) : 4418 - 4423
  • [9] Homo- and nor-plakotenin, new carboxylic acids from the Palauan sponge Plakortis lita
    Qureshi, A
    Stevenson, CS
    Albert, CL
    Jacobs, RS
    Faulkner, DJ
    [J]. JOURNAL OF NATURAL PRODUCTS, 1999, 62 (08): : 1205 - 1207
  • [10] Manganese PNP-pincer catalyzed isomerization of allylic/homo-allylic alcohols to ketones - activity, selectivity, efficiency
    Xia, Tian
    Spiegelberg, Brian
    Wei, Zhihong
    Jiao, Haijun
    Tin, Sergey
    Hinze, Sandra
    de Vries, Johannes G.
    [J]. CATALYSIS SCIENCE & TECHNOLOGY, 2019, 9 (22) : 6327 - 6334
123