Facile synthesis of porous Pt-Pd nanospheres supported on reduced graphene oxide nanosheets for enhanced methanol electrooxidation

被引:134
|
作者
Li, Shan-Shan [1 ]
Lv, Jing-Jing [2 ]
Hu, Yuan-Yuan [1 ]
Zheng, Jie-Ning [1 ]
Chen, Jian-Rong [2 ]
Wang, Ai-Jun [2 ]
Feng, Jiu-Ju [1 ]
机构
[1] Zhejiang Normal Univ, Coll Chem & Life Sci, Jinhua 321004, Peoples R China
[2] Zhejiang Normal Univ, Coll Geog & Environm Sci, Jinhua 321004, Peoples R China
关键词
Reduced graphene oxide nanosheets; Porous nanospheres; Octylphenoxypolye thoxyethanol; Methanol oxidation; Electrocatalysis; OXYGEN REDUCTION; ELECTROCATALYTIC ACTIVITY; CARBON NANOTUBES; HIGH-PERFORMANCE; NANOPARTICLES; ALLOY; OXIDATION; FILMS; CO; NANOCRYSTALS;
D O I
10.1016/j.jpowsour.2013.08.088
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, a simple, facile, and effective wet-chemical strategy was developed in the synthesis of uniform porous Pt-Pd nanospheres (Pt-Pd NSs) supported on reduced graphene oxide nanosheets (RGOs) under ambient temperature, where octylphenoxypolye thoxyethanol (NP-40) is used as a soft template, without any seed, organic solvent or special instruments. The as-prepared nanocomposites display enhanced electrocatalytic activity and good stability toward methanol oxidation, compared with commercial Pd/C and Pt/C catalysts. This strategy may open a new route to design and prepare advanced electrocatalysts for fuel cells. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:213 / 218
页数:6
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