Efficient electrochromic device based on sol-gel prepared WO3 films

被引:42
|
作者
Zhao, Bowen [1 ]
Zhang, Xin [1 ]
Dong, Guobo [2 ]
Wang, Hao [1 ]
Yan, Hui [1 ]
机构
[1] Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
[2] Beihang Univ, Ctr Condensed Matter & Mat Phys, Sch Sci, Beijing 100083, Peoples R China
关键词
Tungsten oxide; Electrochromic; Sol-gel; Annealing; TUNGSTEN-OXIDE FILMS; THIN-FILMS; OPTICAL-PROPERTIES; HIGH-PERFORMANCE; NICKEL-OXIDE; MICROSTRUCTURE; STABILITY; PROGRESS; SURFACE; ARRAYS;
D O I
10.1007/s11581-015-1471-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Tungsten oxide (WO3) films were prepared on indium-tin oxide (ITO) glass by sol-gel method. The influence of annealing temperature on the structural, morphological, optical, electrochemical, and electrochromic properties has been investigated. The film annealed at 250 A degrees C with an amorphous structure exhibits a noticeable electrochromic performance, such as the highest optical modulation of 58.5 % at 550 nm, high electrochemical stability, and excellent reversibility (Q (b)/Q (c) = 96.3 %). An electrochromic (EC) device based on WO3/NiO complementary structure shows improved performance. It exhibits high optical transmittance modulation of 62 % at 550 nm, excellent cycling stability, and relatively fast electrochromic response time (10 s for coloration and 19 s for bleaching).
引用
收藏
页码:2879 / 2887
页数:9
相关论文
共 50 条
  • [1] Efficient electrochromic device based on sol–gel prepared WO3 films
    Bowen Zhao
    Xin Zhang
    Guobo Dong
    Hao Wang
    Hui Yan
    [J]. Ionics, 2015, 21 : 2879 - 2887
  • [2] Electrochromic and structural characteristics of mesoporous WO3 films prepared by a sol-gel method
    Solarska, R
    Alexander, BD
    Augustynski, J
    [J]. JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2004, 8 (10) : 748 - 756
  • [3] Electrochromic and structural characteristics of mesoporous WO3 films prepared by a sol-gel method
    Renata Solarska
    Bruce D. Alexander
    Jan Augustynski
    [J]. Journal of Solid State Electrochemistry, 2004, 8 : 748 - 756
  • [4] Electrochromic and photoelectrochemical characteristics of nanostructured WO3 films prepared by a sol-gel method
    Solarska, R
    Alexander, BD
    Augustynski, J
    [J]. COMPTES RENDUS CHIMIE, 2006, 9 (02) : 301 - 306
  • [5] Electrochromic properties of lithium doped WO3 films prepared by the sol-gel process
    Avellaneda, CO
    Bueno, PR
    Faria, RC
    Bulhoes, LOS
    [J]. ELECTROCHIMICA ACTA, 2001, 46 (13-14) : 1977 - 1981
  • [6] WO3 thin films by sol-gel for electrochromic applications
    Cremonesi, A
    Bersani, D
    Lottici, PP
    Djaoued, Y
    Ashrit, PV
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2004, 345 : 500 - 504
  • [7] The characters of WO3 electrochromic film prepared by sol-gel method
    Ning, Honglong
    Zhang, Xiaochen
    Zhang, Guanguang
    Shi, Muyang
    Huang, Zhiwei
    Ni, Haozhi
    Tao, Ruiqiang
    Yao, Rihui
    Peng, Junbiao
    Fang, Zhiqiang
    [J]. 2018 19TH INTERNATIONAL CONFERENCE ON ELECTRONIC PACKAGING TECHNOLOGY (ICEPT), 2018, : 607 - 609
  • [8] Study of sol-gel prepared nanostructured WO3 thin films and composites for electrochromic applications
    Badilescu, S
    Ashrit, PV
    [J]. SOLID STATE IONICS, 2003, 158 (1-2) : 187 - 197
  • [9] Sol-gel electrochromic WO3 coatings on glass
    Patra, A
    Auddy, K
    Ganguli, D
    Livage, J
    Biswas, PK
    [J]. MATERIALS LETTERS, 2004, 58 (06) : 1059 - 1063
  • [10] Optical and electrochromic properties of sol-gel WO3 films on conducting glass
    Biswas, PK
    Pramanik, NC
    Mahapatra, MK
    Ganguli, D
    Livage, J
    [J]. MATERIALS LETTERS, 2003, 57 (28) : 4429 - 4432