Preparation of highly active zeolite-based hydrodesulfurization catalysts: Zeolite-supported Rh catalysts

被引：0
|
作者：
Sugioka, M
Tochiyama, C
Sado, F
Maesaki, N
机构：
来源：
CATALYSTS IN PETROLEUM REFINING AND PETROCHEMICAL INDUSTRIES 1995 | 1996年 / 100卷
关键词：
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
It was revealed that Rh/USY showed the highest activity among Rh supported on various zeolites and its catalytic activity was higher than commercial CoMo/Al2O3 catalyst for the hydrodesulfurization of thiophene at 400 degrees C. The catalytic activity of Rh/USY decreased gradually with the reaction time. However, the catalyst deactivation of Rh/USY with reaction time was remarkably improved by the addition of small amounts of alkali metal salts. It is concluded that Rh/USY modified with alkali metal salts are potential highly active second generation hydrodesulfurization catalysts for petroleum feedstocks.
引用
收藏
页码：551 / 558
页数：8
相关论文
共 50 条
  • [1] HIGHLY-ACTIVE ZEOLITE-BASED HYDRODESULFURIZATION CATALYSTS
    SUGIOKA, M
    [J]. ERDOL & KOHLE ERDGAS PETROCHEMIE, 1995, 48 (03): : 128 - 132
  • [2] Hydrodesulfurization of Transportation Fuels Over Zeolite-Based Supported Catalysts
    Wang, Yi
    Wang, Binteng
    Rives, Alain
    Sun, Yinyong
    [J]. ENERGY AND ENVIRONMENT FOCUS, 2014, 3 (01) : 45 - 52
  • [3] Review on Hydrodesulfurization over Zeolite-Based Catalysts
    Cui, Tian-You
    Rajendran, Antony
    Fan, Hong-Xia
    Feng, Jie
    Li, Wen-Ying
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2021, 60 (08) : 3295 - 3323
  • [4] HYDRODESULFURIZATION ACTIVITY OF ZEOLITE-SUPPORTED NICKEL AND COBALT SULFIDE CATALYSTS
    WELTERS, WJJ
    KORANYI, TI
    DEBEER, VHJ
    VANSANTEN, RA
    [J]. STUDIES IN SURFACE SCIENCE AND CATALYSIS, 1993, 75 : 1931 - 1934
  • [5] HIGHLY-ACTIVE ZEOLITE-SUPPORTED COPPER(II) OXIDE CATALYSTS
    DAVIES, G
    ABDELFATTAH, TM
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 210 : 201 - COLL
  • [6] Effectiveness of Mo-Ni sulfide clusters in the preparation of zeolite-supported hydrodesulfurization catalysts
    Tatsumi, T
    Taniguchi, M
    Ishige, H
    Ishii, Y
    Murata, T
    Hidai, M
    [J]. APPLIED SURFACE SCIENCE, 1997, 121 : 500 - 504
  • [7] Effectiveness of Mo-Ni sulfide clusters in the preparation of zeolite-supported hydrodesulfurization catalysts
    Univ of Tokyo, Tokyo, Japan
    [J]. Applied Surface Science, 1997, 121-122 : 500 - 504
  • [8] CHARACTERIZATION AND THIOPHENE HYDRODESULFURIZATION ACTIVITY OF NAX ZEOLITE-SUPPORTED MOLYBDENA CATALYSTS
    DAS, D
    DUTTAGUPTA, M
    PALIT, SK
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1994, 67 (11) : 2906 - 2912
  • [9] EXAFS STUDY OF ZEOLITE-SUPPORTED RH CATALYSTS FOR METHANOL CARBONYLATION
    DENLEY, DR
    RAYMOND, RH
    TANG, SC
    [J]. JOURNAL OF CATALYSIS, 1984, 87 (02) : 414 - 423
  • [10] Promotion Effects in the Reduction of NO by CO over Zeolite-Supported Rh Catalysts
    Lepage, Muriel
    Visser, Tom
    Soulimani, Fouad
    Iglesias-Juez, Ana
    Weckhuysen, Bert M.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (05): : 2282 - 2292
12345