A manganese-doped polymeric framework of polyoxotitanate nanoclusters with a narrow band gap

被引：17
|
作者：
Chen, Yang [1 ]
Sokolow, Jesse D. [1 ]
Trzop, Elzbieta [1 ]
Coppens, Philip [1 ]
机构：
[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA
来源：
DALTON TRANSACTIONS | 2013年 / 42卷 / 43期
关键词：
METAL-ORGANIC FRAMEWORK; PHOTOCATALYST; FAMILY; PHASE;
D O I：
10.1039/c3dt52218k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A three-dimensional coordination polymer based on a manganese-doped polyoxotitanate nanocluster, {Ti13Mn4O16[MeC(CH2O)(3)](4)(OEt)(12)Br-4}(infinity), has been synthesized under solvothermal conditions. It is the first framework of doped polyoxotitanate nanoclusters reported in the literature. Compared with anatase, its band gap is reduced from 3.19 to 2.57 eV.
引用
收藏
页码：15285 / 15287
页数：3
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