Discrete Supramolecular Donor-Acceptor Complexes

被引：84

作者：

Gayathri, S. Shankara ^{[2
,3
]}

Wielopolski, Mateusz ^{[2
,3
]}

Perez, Emilio M. ^{[4
]}

Fernandez, Gustavo ^{[4
]}

Sanchez, Luis ^{[4
]}

Viruela, Rafael ^{[1
]}

Orti, Enrique ^{[1
]}

Guldi, Dirk M. ^{[2
,3
]}

Martin, Nazario ^{[4
]}

机构：

[1] Univ Valencia, Inst Ciencia Mol, Paterna 46980, Spain

[2] Univ Erlangen Nurnberg, Dept Chem & Pharm, D-91058 Erlangen, Germany

[3] ICMM, D-91058 Erlangen, Germany

[4] Univ Complutense Madrid, Dept Quim Organ, Fac CC Quim, E-28040 Madrid, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 04期

关键词：

charge transfer; density functional calculations; host-guest systems; photochemistry; pi interactions; PHOTOINDUCED ELECTRON-TRANSFER; EXTENDED TETRATHIAFULVALENE DERIVATIVES; ENERGY; SYSTEMS; COMMUNICATION; RECEPTORS; NANOTUBE; CURVES; CHARGE; DYADS;

D O I：

10.1002/anie.200803984

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) On the ball: Charge transfer occurs readily in tightly interacting complexes formed from π-extended tetrathiafulvalenes, which act as pincerlike receptors, and C60 in a variety of solvents upon photoexcitation (see picture; PET = photoelectron transfer). It should be feasible to construct simple photovoltaic devices from systems based on similar recognition motifs. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：815 / 819

页数：5

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