Synthesis of cyclic sulfones by ring-closing metathesis

被引:63
|
作者
Yao, QW [1 ]
机构
[1] No Illinois Univ, Michael Faraday Labs, Dept Chem & Biochem, De Kalb, IL 60115 USA
关键词
D O I
10.1021/ol017142y
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A general and highly efficient synthesis of cyclic sulfones based on ring-closing metathesis has been developed. The synthetic utility of the resulting cyclic sulfones was demonstrated by their participation in stereoselective Diels-Alder reactions and transformation to cyclic dienes by the Ramberg-Backlund reaction.
引用
收藏
页码:427 / 430
页数:4
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