Separation of zirconium and hafnium using Diphonix® chelating ion-exchange resin

被引：46
|
作者：
Smolik, M. [1 ]
Jakobik-Kolon, A. [1 ]
Poranski, M. [2 ]
机构：
[1] Silesian Tech Univ, Dept Inorgan Chem & Technol, Fac Chem, PL-44100 Gliwice, Poland
[2] Power Res & Testing Co Energopomiar Ltd, PL-44101 Gliwice, Poland
来源：
HYDROMETALLURGY | 2009年 / 95卷 / 3-4期
关键词：
Hafnium; Zirconium; Separation; Ion exchange; Diphonix (R); ANION-EXCHANGE; ACID-SOLUTIONS; EXTRACTION;
D O I：
10.1016/j.hydromet.2008.05.010
中图分类号：
TF [冶金工业];
学科分类号：
0806 ;
摘要：
The sorption behavior and possible separation of zirconium and hafnium from acid solution was studied on Diphonix (R) chelating resin containing diphosphonic, sulfonic and carboxylic acid groups. Sulfuric acid solution was selected and then used in dynamic studies. The effects of acid concentration. temperature and solution flow rate on the separation of Zr and Hf using Diphonix (R) ion-exchanger were investigated. The best separation of these elements was obtained in 0.5 M H(2)SO(4) at 22 degrees C with a linear flow rate < 7.5 cm/h (< 0.79 BV/h). Results show Diphonix (R) resin to be very promising in the separation of zirconium from hafnium. (c) 2008 Elsevier B.V. All rights reserved.
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页码：350 / 353
页数：4
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