Preparation of Metalloporphyrin with Disulfide Bond and Electrocatalytic Reduction of Oxygen

被引：0
|
作者：
Xiu-You, Huang [1 ]
Bing-Cheng, Hu [1 ]
Shi-Chao, Xu [1 ]
机构：
[1] Nanjing Univ Sci & Technol, Coll Chem Engn, Nanjing 210094, Jiangsu, Peoples R China
来源：
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2013年 / 34卷 / 06期
关键词：
Hemin; Porphyrin; Self-assembly; Modified electrode; Electrocatalytic reduction; SELF-ASSEMBLED MONOLAYER; COBALT-PORPHYRIN; GOLD; DEUTEROPORPHYRIN; ELECTRODES; PROPERTY;
D O I：
10.7503/cjcu20120803
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel amino acid derivatised mesoporphyrin Co(II)-[2,7,12,18-tetramethyl-3,8-diethyl-13,17-(propionylaminoethyl-dithio-ethyaminoformylethyl)-29,34-bis-(methoxy-formyl)]-prophyrin [Co(II) MPDTEP, V] was prepared from hemin by a six-steps reaction including deferrization, esterification, catalytic hydrogenation, hydrolyzation, condensation and complexation. The target products were characterized. The effects of the reaction time and temperature on the yields of the product [2,7,12,18-tetramethyl-3,8-diethyl-13,17-(propionylaminoethyl-dithio-ethyaminoformylethyl)-29,34-bis-(methoxy-formyl)]-prophyrin (MPDTEP, IV) were investigated. A gold electrode modified by Co(II) MPDTEP was prepared by self-assembly of disulfide on gold. The Properties of the modified electrode were investigated by FTIR as well as electrochemical methods. This modified electrode was successfully used for the electrocatalytic reduction of oxygen.
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页码：1510 / 1515
页数：6
相关论文
共 22 条
  • [1] Bard A. J., 1980, ELECTROCHEMICAL METH, P633
  • [2] Supramolecular Chemistry of Metalloporphyrins
    Beletskaya, Irina
    Tyurin, Vladimir S.
    Tsivadze, Aslan Yu.
    Guilard, Roger
    Stern, Christine
    [J]. CHEMICAL REVIEWS, 2009, 109 (05) : 1659 - 1713
  • [3] Electronic and structural studies of immobilized thiol-derivatized cobalt porphyrins on gold surfaces
    Berner, Simon
    Lidbaum, Hans
    Ledung, Greger
    Ahlund, John
    Nilson, Katharina
    Schiessling, Joachim
    Gelius, Ulrik
    Baeckvall, Jan-E.
    Puglia, Carla
    Oscarsson, Sven
    [J]. APPLIED SURFACE SCIENCE, 2007, 253 (18) : 7540 - 7548
  • [4] CD-Sensitive Zn-Porphyrin Tweezer Host-Guest Complexes, Part 2: Cis- and Trans-3-Hydroxy-4-aryl/alkyl-β-Lactams. A Case Study
    Chen, Yihui
    Petrovic, Ana G.
    Roje, Marin
    Pescitelli, Gennaro
    Kayser, Margaret M.
    Yang, Yan
    Berova, Nina
    Proni, Gloria
    [J]. CHIRALITY, 2010, 22 (01) : 140 - 152
  • [5] Catalysis of the electroreduction of O2 by cobalt 5,10,15,20-tetraphenylporphyrin dissolved in thin layers of benzonitrile on graphite electrodes
    Chung, TD
    Anson, FC
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2001, 508 (1-2): : 115 - 122
  • [6] Self-assembled monolayer of an iron(III) porphyrin disulphide derivative on gold
    Cordas, CM
    Viana, AS
    Leupold, S
    Montforts, FP
    Abrantes, LM
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2003, 5 (01) : 36 - 41
  • [7] Cui QL, 2011, CHEM J CHINESE U, V32, P2311
  • [8] Degrand D, 1984, J ELECTROANAL CHEM, V169, P259
  • [9] Electrocatalytic oxygen reduction by Co(III) porphyrins incorporated in aerogel carbon electrodes
    Elbaz, L.
    Korin, E.
    Soifer, L.
    Bettelheim, A.
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2008, 621 (01) : 91 - 96
  • [10] Fu YQ, 2002, CHEM J CHINESE U, V23, P2055
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