A highly sensitive and selective off-on fluorescent chemosensor for Al3+ based on naphthalene derivative

被引：36

作者：

Azadbakht, Reza ^{[1
]}

Khanabadi, Javad ^{[1
]}

机构：

[1] Payame Noor Univ, Dept Chem, Tehran, Iran

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 30卷

关键词：

Chemosensor; Naphthalene; Al3+ sensor; Macrocycle; Fluorescence; ALUMINUM; IONS;

D O I：

10.1016/j.inoche.2013.01.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new dialdehyde (D) containing two emissive naphthalene and its [1+1] macrocycle with 1,2-diaminopropane were synthesized and characterized. The macrocycle was studied by H-1 NMR, C-13 NMR, COSY, HSQC, DEPT, mass spectrometry and microanalysis. The influence of metal cations such as Na+, K+, Cs+, Mg2+, Ba2+, Al3+, Pb2+, Cr3+, Mn2+, Fe3+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+ and Ag+ on the photophysical properties of the macrocyclic system in DMF and DMF/H2O (9:1, v/v) mixture was investigated by means of emission spectrophotometry. The macrocycle L was found to be as an effective fluorescent sensor for Al3+ ions. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：21 / 25

页数：5

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