Effects of MgO and TiO2 on the properties of cobalt catalysts for the synthesis of hydrocarbons from CO and H2

被引：1

作者：

Eliseev, O. L. ^{[1
]}

Tsapkina, M. V. ^{[1
]}

Davydov, P. E. ^{[1
]}

Lapidus, A. L. ^{[1
]}

机构：

[1] Russian Acad Sci, Zelinsky Inst Organ Chem, Moscow 119991, Russia

来源：

SOLID FUEL CHEMISTRY | 2015年 / 49卷 / 03期

关键词：

FISCHER-TROPSCH SYNTHESIS;

D O I：

10.3103/S0361521915030052

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It was found that the promotion of Co/Al2O3 catalysts prepared by impregnation with the oxide MgO or TiO2 decreased or increased the reducibility of cobalt, respectively. Both of the promoters decreased the specific activity of the catalyst in the synthesis of hydrocarbons from CO and H-2; this fact can be explained by the formation of larger cobalt crystallites on the surface. The promotion with MgO and TiO2 led to the formation of higher molecular weight hydrocarbons. The highest 86% selectivity for C5+ hydrocarbons was reached on the catalyst containing 1% TiO2, and the chain growth index on this catalyst was 0.88.

引用

页码：147 / 149

页数：3

共 50 条

[1] Effects of MgO and TiO2 on the properties of cobalt catalysts for the synthesis of hydrocarbons from CO and H2
O. L. Eliseev
M. V. Tsapkina
P. E. Davydov
A. L. Lapidus
[J]. Solid Fuel Chemistry, 2015, 49 : 147 - 149
[2] Bimetallic cobalt catalysts for the synthesis of hydrocarbons from CO and H2
Lapidus, AL
Tsapkina, MV
Krylova, AY
Tonkonogov, BP
[J]. USPEKHI KHIMII, 2005, 74 (06) : 634 - 645
[3] Cobalt-zirconium catalysts for the synthesis of hydrocarbons from CO and H2
O. L. Eliseev
D. Zh. Latypova
E. M. Movsumzade
V. S. Dorokhov
V. M. Kogan
A. L. Lapidus
[J]. Solid Fuel Chemistry, 2013, 47 : 98 - 102
[4] Cobalt-Zirconium Catalysts for the Synthesis of Hydrocarbons from CO and H2
Eliseev, O. L.
Latypova, D. Zh.
Movsumzade, E. M.
Dorokhov, V. S.
Kogan, V. M.
Lapidus, A. L.
[J]. SOLID FUEL CHEMISTRY, 2013, 47 (02) : 98 - 102
[5] The Influence of Platinum on the Catalytic Properties of Bifunctional Cobalt Catalysts for the Synthesis of Hydrocarbons from CO and H2
Yakovenko, Roman E.
Zubkov, Ivan N.
Papeta, Ol'ga P.
Kataria, Yash V.
Bakun, Vera G.
Svetogorov, Roman D.
Savost'yanov, Alexander P.
[J]. CATALYSTS, 2024, 14 (06)
[6] Synthesis of aromatic hydrocarbons from CO and H2 in the presence of Co-MgO/NTsVM catalysts
Dergachev, A.A.
Krylova, M.V.
Tonkonogov, B.P.
Silakova, A.A.
Krylova, A.Yu.
Lapidus, A.L.
[J]. Khimiya Tverdogo Topliva, 2002, (03): : 40 - 47
[7] INFLUENCE OF PHYSIOCHEMICAL CHARACTERISTICS ON PROPERTIES OF CO CATALYSTS FOR SYNTHESIS OF HYDROCARBONS FROM CO AND H2
LAPIDUS, AL
BUDTSOV, VS
SAVOSTYANOV, AP
KRYLOVA, AY
MEZHOV, VD
BAKUN, VG
[J]. PETROLEUM CHEMISTRY, 1991, 31 (05) : 623 - 626
[8] On mechanism of formation of liquid hydrocarbons from CO and H2 on cobalt catalysts
[J]. 2000, MAIK Nauka (44):
[9] PROPERTIES OF CO-AL2O3 CATALYSTS IN THE SYNTHESIS OF HYDROCARBONS FROM CO AND H2
KHOANG, CI
KRYLOVA, AY
SALEKHUDDIN, SM
LAPIDUS, AL
[J]. BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1983, 32 (09): : 1829 - 1831
[10] Effects of Ruthenium on the Catalytic Performance of Cobalt-Based Hybrid Catalysts for Synthesis of Hydrocarbons from CO and H2
Sulima, S. I.
Bakun, V. G.
Zubkov, I. N.
Savost'yanov, A. P.
Yakovenko, R. E.
[J]. PETROLEUM CHEMISTRY, 2023, 63 (07) : 746 - 758

← 1 2 3 4 5 →