A new co-solvent method for the green production of biodiesel fuel - Optimization and practical application

被引:65
|
作者
Le Tu Thanh [1 ,4 ]
Okitsu, Kenji [2 ]
Sadanaga, Yasuhiro [3 ]
Takenaka, Norimichi [3 ]
Maeda, Yasuaki [1 ]
Bandow, Hiroshi [3 ]
机构
[1] Osaka Prefecture Univ, Res Org Univ Community Collaborat, Naka Ku, Sakai, Osaka 5998531, Japan
[2] Osaka Prefecture Univ, Dept Mat Sci, Grad Sch Engn, Naka Ku, Sakai, Osaka 5998531, Japan
[3] Osaka Prefecture Univ, Dept Appl Chem, Grad Sch Engn, Naka Ku, Sakai, Osaka 5998531, Japan
[4] Vietnam Natl Univ Ho Chi Minh City, Univ Sci, Fac Environm Sci, Ho Chi Minh City, Vietnam
基金
日本科学技术振兴机构;
关键词
Biodiesel production; Co-solvent method; Waste cooking oil; Jatropha curcas oil; Transesterification; SEED OIL; VEGETABLE-OIL; RAPESEED OIL; TRANSESTERIFICATION; CATALYSTS; SUNFLOWER; GLYCEROL; BIOFUELS; YIELDS; ESTER;
D O I
10.1016/j.fuel.2012.09.029
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
An homogeneous reaction process using acetone as a co-solvent for the transesterification of vegetable oils with methanol in the presence of potassium hydroxide catalyst has been developed. The effects of the main parameters, such as the amounts of acetone and KOH, the molar ratio of methanol to oil and the reaction temperature, on fatty acid methyl esters (FAME) yield were investigated. The optimal conditions were: 25 wt.% acetone and 1.0 wt.% KOH catalyst in oil; a molar ratio of methanol to oil of 4.5: 1; and a reaction temperature of 25 degrees C. Under these conditions, the conversion of vegetable oil to FAME exceeded 98% after 30 min. This method was applied to produce biodiesel fuel (BDF) from waste cooking oil (WCO), canola, catfish and Jatropha curcas oils, with the main product quality factors satisfying the JIS 2390 BDF standards. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:742 / 748
页数:7
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