Synthesis and crystal structure of RE[CH2(CH2)(4)CONC4H9](3)(NO3)(3)(RE=Dy, La)

被引：0

作者：

Wang, HZ ^{[1
]}

Xu, QF ^{[1
]}

Qian, P ^{[1
]}

Sun, JP ^{[1
]}

Cao, ZB ^{[1
]}

机构：

[1] SUZHOU UNIV,DEPT CHEM,SUZHOU 215006,PEOPLES R CHINA

来源：

JOURNAL OF RARE EARTHS | 1997年 / 15卷 / 02期

关键词：

rare earths; La; Dy; complex synthesis; crystal structure; butyl-caprolactam;

D O I：

暂无

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The structure of complexes Dy[CH2(CH2)(4)CONC4H9](3) (NO3)(3) and La[CH2 (CH2)(4)CONC4H9](3)(NO3)(3) was studied by single crystal X-ray diffraction. The two compounds are isostructural and all form monoclinic crystal with space group P2(1)/c. The crystal data Dy [La]* : a=1.8564(3)[1.8857(2)] nm, b=0.9769(2) [0.9834(1)] nm, c=2.1863(6) [2.2008(7)] nm, beta=96.08(2)[95.72(2)]degrees, V=3.942(1)[4.061(1)] nm(3), Z=4. Dy3+ [La3+] is coordinated through three carbonyls of the three organic ligands and the ti;ree nitrates are all bidentate. So each Dy3+[La3+] is coordinated by nine oxygen atoms which form a distorted tricapped trigonal prism.

引用

页码：81 / 85

页数：5

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