Centrosymmetric molecules for second harmonic generation

被引:29
|
作者
Ashwell, GJ
机构
[1] Centre for Molecular Electronics, Cranfield University
关键词
D O I
10.1002/adma.19960080314
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Research News: The requirement of a non-centrosymmetric structure for second harmonic generation (SHG) was until recently assumed necessarily to apply to the smallest building block, the molecule. However, non-centrosymmetric aggregates of centrosymmetric molecules can exist, and their SHG properties are considered here. Derivatives of squaraines are taken as examples. Finally, the role of intermolecular charge transfer in Langmuir-Blodgett film-forming materials for SHG-both within the monolayers and across the boundary-is discussed.
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页码:248 / +
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