Li3Al(MoO2)2O2(AsO4)2

被引：3
|
作者：
Hajji, Mounir [1 ]
Zid, Mohamed Faouzi [1 ]
Driss, Ahmed [1 ]
机构：
[1] Univ Tunis ElManar, Fac Sci, Lab Mat & Cristallochim, Elmanar Tunis 2092, Tunisia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
CRYSTAL-STRUCTURE; CATHODE;
D O I：
10.1107/S160053680900631X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Single crystals of trilithium(I) aluminium(III) bis[-dioxidomolybdenum(VI)] dioxide bis[arsenate(V)], Li3Al-Mo2As2O14, have been prepared by solid-state reaction at 788 K. The structure consists of AsO4 tetrahedra, AlO6 octahedra and Mo2O10 groups sharing corners to form a three-dimensional framework containing channels running respectively along the [100] and [010] directions, where the Li+ ions are located. This structure is compared with compounds having (MX2O12)(n) chains (M = Mo, Al and X = P, As) and others containing M2O10 (M = Mo, Fe) dimers.
引用
收藏
页码：I21 / U150
页数：10
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