Efficient isonitrile hydration through encapsulation within a hexameric self-assembled capsule and selective inhibition by a photo-controllable competitive guest

被引：53

作者：

Bianchini, Giulio ^{[1
]}

La Sorella, Giorgio ^{[1
]}

Canever, Nicolo ^{[1
]}

Scarso, Alessandro ^{[1
]}

Strukul, Giorgio ^{[1
]}

机构：

[1] Univ Ca Foscari Venezia, Dipartimento Sci Mol & Nanosistemi, I-30123 Venice, Italy

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 46期

关键词：

CARBOXYLIC-ACIDS; ISOCYANIDES; LIGHT; DIARYLETHENES; CONVERSION; ALCOHOLS;

D O I：

10.1039/c3cc42233j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic hydration of neutral isonitriles to yield the corresponding N-formylamides was achieved by reversible encapsulation in a self-assembled hexameric resorcin[4] arene capsule. Encapsulation of a photochromic dithienylethene bis-cation provides different levels of competitive inhibition depending on the geometry assumed by the cationic inhibitor.

引用

页码：5322 / 5324

页数：3

共 6 条

[1] Substrate selective amide coupling driven by encapsulation of a coupling agent within a self-assembled hexameric capsule
Giust, Sonia
La Sorella, Giorgio
Sperni, Laura
Strukul, Giorgio
Scarso, Alessandro
[J]. CHEMICAL COMMUNICATIONS, 2015, 51 (09) : 1658 - 1661
[2] Efficient epoxide isomerization within a self-assembled hexameric organic capsule
Caneva, Thomas
Sperni, Laura
Strukul, Giorgio
Scarso, Alessandro
[J]. RSC ADVANCES, 2016, 6 (87): : 83505 - 83509
[3] Encapsulation and Enhanced Luminescence Properties of IrIII Complexes within a Hexameric Self-Assembled Capsule
Horiuchi, Shinnosuke
Tanaka, Hirotaka
Sakuda, Eri
Arikawa, Yasuhiro
Umakoshi, Keisuke
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (49) : 17533 - 17537
[4] Supramolecular Graft Copolymerization of a Polyester by Guest-Selective Encapsulation of a Self-Assembled Capsule
Tsunoda, Yuta
Takatsuka, Mei
Sekiya, Ryo
Haino, Takeharu
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (10) : 2613 - 2618
[5] Encapsulation Studies of Cationic Gold Complexes within a Self-Assembled Hexameric Resorcin[4]arene Capsule
Adriaenssens, Louis
Escribano-Cuesta, Ana
Homs, Anna
Echavarren, Antonio M.
Ballester, Pablo
[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2013, 2013 (08) : 1494 - 1500
[6] Reversible encapsulation of a nitrate guest via hydrogen-bonded self-assembled capsule formation by a flexible tripodal receptor in polar solvent through dynamic self-assembly
Singh, Ashutosh S.
Sun, Shih-Sheng
[J]. RSC ADVANCES, 2012, 2 (25): : 9502 - 9510

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