Reaction dynamics of Ca(4s3d1D2)+CH4→CaH(X2Σ+)+CH3:: Reaction pathway and energy disposal for the CaH product -: art. no. 024304

The reaction pathway for Ca(4s3d D-1(2))+CH4 -> CaH(X (2)Sigma(+))+CH3 has been investigated by using a pump-probe technique in combination with potential-energy surface (PES) calculations. The nascent product distributions of CaH have been characterized with Boltzmann rotational temperatures of 1013 +/- 102 and 834 +/- 70 K for the v=0 and 1 levels, respectively, and a Boltzmann vibrational temperature of 1313 +/- 173 K. The rotational and vibrational energy partitions in CaH have been estimated to be 461 +/- 45 and 252 +/- 15 cm(-1), respectively. According to the PES calculations, the pathway favors an insertion mechanism. Ca(3 D-1(2)) approaches CH4 along an attractive potential surface in a C-2v (or C-s) symmetry and then the collision complex undergoes nonadiabatic transition to the reactive ground-state surface. An Arrhenius plot shows a potential-energy requirement of 2695 +/- 149 cm(-1), which accounts for the endothermicity of 2930 cm(-1) for the reaction scheme. The Ca-C bond distance in the transition state structure is short enough to allow for tight orbital overlap between CaH and CH3. The strong coupling between the moieties renders the energy transfer sufficient from CaH into the CH3 radical. As compared to the Ca(4 P-1(1)) reaction, the dissociation lifetime of the intermediate complex with less excess energy is prolonged so as to cause much less vibrational energy disposal into CaH. (c) 2006 American Institute of Physics.