Catalytic asymmetric cyclopropanation of electron deficient alkenes mediated by chiral sulfides

被引：49
|
作者：
Aggarwal, VK [1 ]
Smith, HW [1 ]
Jones, RVH [1 ]
Fieldhouse, R [1 ]
机构：
[1] ZENECA PROC TECHNOL DEPT,GRANGEMOUTH,STIRLING,SCOTLAND
来源：
CHEMICAL COMMUNICATIONS | 1997年 / 18期
关键词：
D O I：
10.1039/a704214k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Catalytic asymmetric cylopropanation of enones has been achieved using diazo compounds, catalytic quantities of a metal catalyst and a camphor-derived thioacetal; this sulfide shows exceptionally high levels of enantioselectivity.
引用
收藏
页码：1785 / 1786
页数：2
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