Electrooxidation of p-nitrophenol on organobentonite modified electrodes

被引：15
|
作者：
Abu Rabi-Stankovic, A. [1 ]
Mojovic, Z. [1 ]
Milutinovic-Nikolic, A. [1 ]
Jovic-Jovicic, N. [1 ]
Bankovic, P. [1 ]
Zunic, M. [1 ]
Jovanovic, D. [1 ]
机构：
[1] Univ Belgrade, Inst Chem Technol & Met, Ctr Catalysis & Chem Engn, Belgrade 11000, Serbia
来源：
APPLIED CLAY SCIENCE | 2013年 / 77-78卷
关键词：
Organobentonites; Modified electrode; Para-nitrophenol; Electrooxidation; ELECTROCHEMICAL DETERMINATION; PHENOLIC-COMPOUNDS; CLAY-FILM; ADSORPTION; ORGANOCLAYS; OXIDATION; WATER; DYE;
D O I：
10.1016/j.clay.2013.04.003
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A natural bentonite, modified with different quaternary ammonium cations, hexadecyl trimethylammonium, (HDTMA), dodecyl trimethylammonium (DTMA) and tetramethylammonium (TMA), was used as an electrode material in a p-nitrophenol (p-NP) electrooxidation. On the basis of electrochemical response, TMA-modified bentonite (TMA-B) electrode was chosen for further investigations. The influence of TMA loading on the electrochemical properties of the TMA-B electrodes toward p-NP electrooxidation was examined. Electrode sensitivity toward p-NP was performed. The detection limit for p-NP of 1 . 10(-6) mol dm(-3) was obtained. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：61 / 67
页数：7
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