Alkylpalladium N-Heterocyclic Carbene Complexes: Synthesis, Reactivity, and Catalytic Properties

被引：31

作者：

Esposito, Oriana ^{[2
]}

Gois, Pedro M. P. ^{[1
,2
,3
]}

Lewis, Alexandra K. de K. ^{[1
]}

Caddick, Stephen ^{[1
]}

Cloke, F. Geoffrey N. ^{[2
]}

Hitchcock, Peter B. ^{[2
]}

机构：

[1] UCL, Dept Chem, London WC1H OAJ, England

[2] Univ Sussex, Sch Life Sci, Dept Chem & Biochem, Brighton BN1 9QJ, E Sussex, England

[3] Inst Super Tecn, CQFM, Dept Engn Quim & Biol, P-1049001 Lisbon, Portugal

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 24期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1021/om800455h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dimers [trans-[(neopentyl)Pd(mu-Cl)(I(t)lBu)](2), 2, and (cis-[(neopentyl)Pd(mu-Cl)(IPr)](2), 3 ((IBu)-Bu-t = 1,3-bis-tert-butylimidazol-2-ylidene, IPr = 1,3-bis-2,6-diidopropylimidazol-2-ylidene), have been synthesized from [Pd(neopentyl)(Cl)(1,5-COD)], and their reactivity toward a variety of nucleophiles has been evaluated. In particular, this study revealed that 2 can be readily cleaved by primary and secondary amines, affording stable transamination products, which are surprisingly resistant to deprotonation. Dimer 3 was subsequently used as a catalyst in a series of Buchwald-Hartwig amination reactions of aryl chlorides.

引用

页码：6411 / 6418

页数：8

共 50 条

[1] Synthesis and reactivity of alkylpalladium N-heterocyclic carbene complexes
Esposito, Oriana
Lewis, Alexandra K. de K.
Hitchcock, Peter B.
Caddick, Stephen
Cloke, F. Geoffrey N.
[J]. CHEMICAL COMMUNICATIONS, 2007, (11) : 1157 - 1159
[2] N-heterocyclic carbene ruthenium complexes: Synthesis and catalytic properties
Dragutan, Ileana
Dragutan, Valerian
Delaude, Lionel
Demonceau, Albert
Noels, Alfred F.
[J]. REVUE ROUMAINE DE CHIMIE, 2007, 52 (11) : 1013 - 1025
[3] Synthesis and reactivity of triethylborane adduct of N-heterocyclic carbene:: versatile synthons for synthesis of N-heterocyclic carbene complexes
Yamaguchi, Y
Kashiwabara, T
Ogata, K
Miura, Y
Nakamura, Y
Kobayashi, K
Ito, T
[J]. CHEMICAL COMMUNICATIONS, 2004, (19) : 2160 - 2161
[4] Synthesis, characterization, electrochemical properties and catalytic reactivity of N-heterocyclic carbene-containing diiron complexes
Wang, Yanhong
Zhang, Tianyong
Li, Bin
Jiang, Shuang
Sheng, Liao
[J]. RSC ADVANCES, 2015, 5 (37): : 29022 - 29031
[5] Butylene linked palladium N-heterocyclic carbene complexes: Synthesis and catalytic properties
Demir, Serpil
Ozdemir, Ismail
Arslan, Hakan
VanDerveer, Don
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (13) : 2589 - 2593
[6] Palladium N-heterocyclic carbene complexes: Synthesis, characterization and catalytic properties in amination
Ozdemir, Ismail
Demir, Serpil
Sahin, Onur
Buyukgungor, Orhan
Cetinkaya, Bekir
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2010, 695 (10-11) : 1555 - 1560
[7] Synthesis, characterization and catalytic properties of cationic N-heterocyclic carbene silver complexes
Atli, Deniz Demir
[J]. TURKISH JOURNAL OF CHEMISTRY, 2021, 45 (03) : 577 - +
[8] Stability and reactivity of N-heterocyclic carbene complexes
Crudden, CM
Allen, DP
[J]. COORDINATION CHEMISTRY REVIEWS, 2004, 248 (21-24) : 2247 - 2273
[9] Piano-stool N-heterocyclic carbene iron complexes: Synthesis, reactivity and catalytic applications
Johnson, Chloe
Albrecht, Martin
[J]. COORDINATION CHEMISTRY REVIEWS, 2017, 352 : 1 - 14
[10] Carbene complexes of rhodium and iridium from tripodal N-heterocyclic carbene ligands:: Synthesis and catalytic properties
Mas-Marzá, E
Poyatos, M
Sanaú, M
Peris, E
[J]. INORGANIC CHEMISTRY, 2004, 43 (06) : 2213 - 2219

← 1 2 3 4 5 →