Spectrophotometric methods for the determination of aniline in water

被引:0
|
作者
Yang, XF [1 ]
Zhao, MP [1 ]
Li, YZ [1 ]
Zhang, XX [1 ]
Chang, WB [1 ]
机构
[1] Peking Univ, Coll Chem & Mol Engn, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China
关键词
aniline; guaiacol; 8-hydroxy-quinoline; 1-naphthol; spectrophotometry;
D O I
暂无
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Three kinds of new spectrophotometric methods for determining trace aniline in water were proposed. Aniline is coupled with guaiacol 8-hydroxy-quinoline or 1-naphthol in alkaline medium (pH = 12.2). The formed azo compounds have maximum absorption at 452,482 and 497 nm respectively against reagent blanks, Compared with N-(1-naphthyl)-ethylenediamine spectrophotometric method, these new methods are more convenient, rapid and sensitive. The limits of detection are 8.6, 10 and 14 mug/L, Beer's law is valid in the range of 0 similar to 5.6, 0 similar to 4.8 and 0 similar to 3.2 mg/L respectively. These new methods have been successfully applied to the determination of aniline in environmental water.
引用
收藏
页码:540 / 543
页数:4
相关论文
共 6 条
  • [1] SPECTROPHOTOMETRIC DETERMINATION OF ANILINE IN AIR AND WATER VIA OXIDATIVE COUPLING USING GUAIACOL
    AMLATHE, S
    GUPTA, VK
    [J]. MICROCHEMICAL JOURNAL, 1991, 43 (03) : 208 - 212
  • [2] *HANGZH U DEP CHEM, 1997, BAS KNOWL SAF NOT, P339
  • [3] LU Q, 2001, J ANAL SCI, V17, P138
  • [4] YUAN CG, 1994, J ENV CHEM, V13, P355
  • [5] ZHANG ZX, 1990, QUANTITATIVE ANAL OR, P326
  • [6] 1996, COMPILE NATL STANDAR, P169