Effects of SnO on structure and properties of borosilicate glasses

被引：2
|
作者：
Lu Ping [1 ]
Cneng Jinshu [1 ]
Wan Junpeng [1 ]
机构：
[1] Wuhan Univ Technol, Minist Educ, Key Lab Silicate Meterials Sci & Engn, Wuhan 430070, Peoples R China
来源：
JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION | 2008年 / 23卷 / 04期
关键词：
borosilicate glasses; SnO; structure;
D O I：
10.1007/s11595-006-4547-3
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Tin was found in the bottom of float borosilicate glasses. To simulate the enriched amounts of SnO found on the surface of the float borosilicate glasses, a series of glasses were produced in which the stannous concentration was varied from 0.1 wt% to 9.0 wt%, while the relative concentration of other components were held constant. Infrared spectra were obtained to probe the effect of increased amounts of SnO on the structure of the glass samples. The results show that SnO plays the role of an intermediate in glasses studied. When FO/SnO>1.0, SnO takes the role of network-former. And when FO/SnO<1.0, SnO can give the free oxygen as network-modifier. Besides, SnO has intensive effect on thermal performance of borosilicate glasses.
引用
收藏
页码：547 / 550
页数：4
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