METAL-ORGANIC FRAMEWORKS AND THEIR APPLICATIONS IN CATALYSIS

被引：18

作者：

Dantas Ramos, Andre Luis ^{[1
]}

Tanase, Stefania ^{[2
]}

Rothenberg, Gadi ^{[2
]}

机构：

[1] Univ Fed Sergipe, Dept Engn Quim, BR-49100000 Sao Cristovao, SE, Brazil

[2] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1098 XH Amsterdam, Netherlands

来源：

QUIMICA NOVA | 2014年 / 37卷 / 01期

关键词：

carboxylate linker; lanthanide; vanadium; INFINITE POLYMERIC FRAMEWORKS; ION-EXCHANGE; HYDROTHERMAL SYNTHESIS; ASYMMETRIC CATALYSIS; CRYSTAL-STRUCTURE; HYDROGEN STORAGE; BUILDING UNITS; VANADIUM; DESIGN; CHEMISTRY;

D O I：

10.1590/S0100-40422014000100021

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-organic frameworks (MOFs) form a new class of materials with well-defined yet tunable properties. These are crystalline, highly porous and exhibit strong metal-ligand interactions. Importantly, their physical and chemical properties, including pore size, pore structure, acidity, and magnetic and optical characteristics, can be tailored by choosing the appropriate ligands and metal precursors. Here we review the key aspects of synthesis and characterization of MOFs, focusing on lanthanide-based and vanadium-based materials. We also outline some of their applications in catalysis and materials science.

引用

页码：123 / 133

页数：11

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