Quantification of rate acceleration in asymmetric catalytic hydrogenation

被引：13
|
作者：
Murzin, Dmitry Yu. [1 ]
机构：
[1] Abo Akad Univ, Proc Chem Ctr, Lab Ind Chem & React Engn, FIN-20500 Turku, Finland
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2008年 / 289卷 / 1-2期
关键词：
asymmetric catalysis; rate acceleration; kinetic model;
D O I：
10.1016/j.molcata.2008.04.016
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A quantitative model is advanced for asymmetric catalytic hydrogenation allowing estimation of the ratio between the rate constants in the absence and presence of the modifier. Comparison between the model and experimental data for 1,2-phenyl-propanedione is given. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：91 / 94
页数：4
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