Self-Healing Polymers via Supramolecular Forces

被引：494

作者：

Herbst, Florian ^{[1
]}

Doehler, Diana ^{[1
]}

Michael, Philipp ^{[1
]}

Binder, Wolfgang H. ^{[1
]}

机构：

[1] Univ Halle Wittenberg, Inst Chem, D-06120 Halle, Saale, Germany

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2013年 / 34卷 / 03期

关键词：

dynamics; hydrogen bonding; pi-pi interaction; self-healing polymer; supramolecular network; CROSS-LINKED NETWORKS; PI-PI STACKING; THERMOPLASTIC ELASTOMERS; VISCOELASTIC PROPERTIES; MECHANICAL-PROPERTIES; TEMPERATURE-DEPENDENCE; COORDINATION POLYMERS; BUILDING-BLOCKS; CHAIN EXTENSION; CLICK CHEMISTRY;

D O I：

10.1002/marc.201200675

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

As polymers and polymeric materials are "the" smart invention and technological driving force of the 20th century, the quest for self-healing or self-repairing polymers is strong. The concept of supramolecular self-healing materials relies on the use of noncovalent, transient bonds to generate networks, which are able to heal the damaged site, putting aspects of reversibility and dynamics of a network as crucial factors for the understanding and design of such self-healing materials. This Review describes recent examples and concepts of supramolecular polymers based on hydrogen bonding, pi-pi interactions, ionomers, and coordinative bonds, thus convincingly discussing the advantages and versatility of these supramolecular forces for the design and realization of self-healing polymers.

引用

页码：203 / 220

页数：18

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