Large-area functionalized CVD graphene for work function matched transparent electrodes

被引：48
|
作者：
Bointon, Thomas H. [1 ]
Jones, Gareth F. [1 ]
De Sanctis, Adolfo [1 ]
Hill-Pearce, Ruth [2 ]
Craciun, Monica F. [1 ]
Russo, Saverio [1 ]
机构：
[1] Univ Exeter, Coll Engn Math & Phys Sci, Ctr Graphene Sci, Exeter EX4 4QF, Devon, England
[2] Natl Phys Lab, Teddington TW11 0LW, Middx, England
来源：
SCIENTIFIC REPORTS | 2015年 / 5卷
基金：
英国工程与自然科学研究理事会;
关键词：
INTERCALATION; OXIDE;
D O I：
10.1038/srep16464
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
The efficiency of flexible photovoltaic and organic light emitting devices is heavily dependent on the availability of flexible and transparent conductors with at least a similar workfunction to that of Indium Tin Oxide. Here we present the first study of the work function of large area (up to 9 cm(2)) FeCl3 intercalated graphene grown by chemical vapour deposition on Nickel, and demonstrate values as large as 5.1 eV. Upon intercalation, a charge density per graphene layer of 5.10(13)+/- 5.10(12) cm(-2) is attained, making this material an attractive platform for the study of plasmonic excitations in the infrared wavelength spectrum of interest to the telecommunication industry. Finally, we demonstrate the potential of this material for flexible electronics in a transparent circuit on a polyethylene naphthalate substrate.
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收藏
页数：6
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