Deuterium substitution effects on the structural and magnetic phase transitions of a hydrogen-bonded coordination polymer, bis(glycolato)copper(II)

被引：6

作者：

Yoneyama, Shota ^{[1
]}

Kodama, Takeshi ^{[1
]}

Kikuchi, Koichi ^{[1
]}

Fujisawa, Takumi ^{[2
]}

Yamaguchi, Akira ^{[2
]}

Sumiyama, Akihiko ^{[2
]}

Shuku, Yoshiaki ^{[3
]}

Aoyagi, Shinobu ^{[4
]}

Fujita, Wataru ^{[4
]}

机构：

[1] Tokyo Metropolitan Univ, Dept Chem, 1-1 Minami Osawa, Hachioji, Tokyo 1920397, Japan

[2] Univ Hyogo, Dept Mat Sci, 3-2-1 Kouto, Kamigori, Hyogo 6781297, Japan

[3] Nagoya Univ, Dept Chem, Chikusa Ku, Furo Cho, Nagoya, Aichi 4648602, Japan

[4] Nagoya City Univ, Dept Informat & Basic Sci, Mizuho Ku, 1 Yamanohata,Mizuho Cho, Nagoya, Aichi 4678501, Japan

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 42期

关键词：

CRYSTAL; FERROELECTRICITY; COMPLEXES; CONDUCTOR;

D O I：

10.1039/c6dt03592b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bis(glycolato)copper(II) [Cu(HOCH2CO2)(2)] shows a structural phase transition around 220 K under cooling and 270 K under heating, and ferromagnetic ordering at 1.1 K. Deuterium substitution of the hydroxyl groups in it induced a large shift in the structural transition temperature while no shift in the ferromagnetic transition temperature took place.

引用

页码：16774 / 16778

页数：5

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