Palladium-catalyzed selective synthesis of unsymmetrical biaryls from aryl halides or triflates and organomanganese reagents

被引:23
|
作者
Riguet, E [1 ]
Alami, M [1 ]
Cahiez, G [1 ]
机构
[1] ECOLE SUPER CHIM ORGAN & MINERALE,DEPT CHIM,F-95092 CERGY,FRANCE
关键词
D O I
10.1016/S0040-4039(97)00940-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Various functionalized unsymmetrical biaryls can be prepared in good to excellent isolated yields by palladium-catalyzed coupling reaction of aryl manganese chloride with aryl iodides, bromides or triflates. The reaction takes place rapidly and cleanly under mild conditions by using only 1% of palladium complexes. (C) 1997 Published by Elsevier Science Ltd.
引用
收藏
页码:4397 / 4400
页数:4
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