Effect of carbon support nature and palladium content on the properties of Pd/C catalysts in hydrogenation of benzaldehyde

被引：12

作者：

Belskaya, O. B. ^{[1
]}

Mironenko, R. M. ^{[1
]}

Likholobov, V. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Inst Hydrocarbon Proc, Omsk 644040, Russia

来源：

THEORETICAL AND EXPERIMENTAL CHEMISTRY | 2013年 / 48卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

benzaldehyde; catalytic hydrogenation; supported palladium catalysts; carbon supports; NANOPARTICLES; ALDEHYDES;

D O I：

10.1007/s11237-013-9285-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the series of studied Pd/C catalysts, the highest selectivity for benzyl alcohol formation with complete conversion of benzaldehyde was demonstrated by the sample containing 1% palladium supported on carbon nanotubes when the reaction was carried out at 40 A degrees C and 0.5 MPa. The 0.3% Pd/C catalysts have low activity. Increasing the palladium content and raising the reaction temperature leads to an increase in the toluene fraction in the reaction products.

引用

下载

页码：381 / 385

页数：5

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