Metastable Interwoven Mesoporous Metal-Organic Frameworks

被引：63
|
作者：
He, Yabing [1 ,2 ]
Guo, Zhiyong [2 ]
Xiang, Shengchang [3 ]
Zhang, Zhangjing [3 ]
Zhou, Wei [4 ,5 ]
Fronczek, Frank R. [6 ]
Parkin, Sean [7 ]
Hyde, Stephen T. [8 ]
O'Keeffe, Michael [9 ]
Chen, Banglin [2 ]
机构：
[1] Zhejiang Normal Univ, Coll Chem & Life Sci, Jinhua 321004, Peoples R China
[2] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA
[3] Fujian Normal Univ, Coll Chem & Mat, Fuzhou 350007, Peoples R China
[4] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA
[5] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA
[6] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA
[7] Univ Kentucky, Dept Chem, Lexington, KY 40506 USA
[8] Australian Natl Univ, Dept Appl Math, Canberra, ACT, Australia
[9] Arizona State Univ, Dept Chem & Biochem, Tempe, AZ 85287 USA
来源：
INORGANIC CHEMISTRY | 2013年 / 52卷 / 19期
关键词：
HIGHLY SELECTIVE SEPARATION; METHANE STORAGE; CO2; ADSORPTION; GAS SORPTION; HYDROGEN; EXCHANGE; POROSITY; TRICARBOXYLATE; ENHANCEMENT; ACTIVATION;
D O I：
10.1021/ic401870e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three isostructural interwoven 3,4-connected mesoporous metal-organic frameworks of pto-a topology (UTSA-28-Cu, UTSA-28-Zn, and UTSA-28-Mn) were synthesized and structurally characterized. Because of their metastable nature, their gas sorption properties are highly dependent on the metal ions and activation profiles. The most stable, UTSA-28a-Cu, exhibits promising gas storage and separation capacities.
引用
收藏
页码：11580 / 11584
页数：5
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