This paper first reports the syntheses and spectral character of his CN, N'-ethylene-2, 2'-(phenylmethylene)bis(3,4-dimethylpyrrole-5-aldimino)]monometallic complexes MH2L[M = Mn(II), Fe(III)Cl, Cr(III)Cl, Cu(II), Co(II), Ni(II), Zn(II)] and dimetallic complexes MnML[M=Fe(III)Cl, Cr(III)Cl, Cu(I), Co(II), Ni(II), Zn(II)].