MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification

被引：231

作者：

Canivet, Jerome ^{[1
]}

Aguado, Sonia ^{[1
]}

Schuurman, Yves ^{[1
]}

Farrusseng, David ^{[1
]}

机构：

[1] Univ Lyon 1, CNRS, Inst Rech Catalyse & Environm Lyon IRCELYON, F-69626 Villeurbanne, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 11期

基金：

欧盟第七框架计划;

关键词：

METAL-ORGANIC FRAMEWORKS; SURFACE ORGANOMETALLIC CHEMISTRY; NICKEL-COMPLEXES BEARING; HIGHER OLEFINS PROCESS; HETEROGENEOUS CATALYSIS; METALLOCENE CATALYSTS; DIIMINE CATALYSTS; OLIGOMERIZATION; POLYMERIZATION; SILICA;

D O I：

10.1021/ja312120x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The one-pot postfunctionalization allows anchoring a molecular nickel complex into a mesoporous metal-organic framework (Ni@(Fe)MIL-101). It is generating a very active and reusable catalyst for the liquid-phase ethylene dimerization to selectively form 1-butene. Higher selectivity for 1-butene is found using the Ni@(Fe)MIL-101 catalyst than reported for molecular nickel diimino complexes.

引用

页码：4195 / 4198

页数：4

共 29 条

[1] Computational study of A MOF-supported single site Ni catalyst for ethylene dimerization
Ye, Jingyun
League, Aaron
Truhlar, Donald
Cramer, Christopher
Gagliardi, Laura
Bernales, Varinia
Farha, Omar
Hupp, Joseph
Li, Zhanyong
Prats, Ana E. Platero
Chapman, Karena
Camaioni, Donald
Fulton, John
Lercher, Johannes
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
[2] Computational study of MOF-supported metal catalysts for ethylene dimerization
Ye, Jingyun
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 256
[3] Computational screening of MOF-supported transition metal catalysts for activity and selectivity in ethylene dimerization
Ye, Jingyun
Gagliardi, Laura
Cramer, Christopher J.
Truhlar, Donald G.
[J]. JOURNAL OF CATALYSIS, 2018, 360 : 160 - 167
[4] Single-site supported catalysts for ethylene polymerization
Muñoz-Escalona, A
Méndez, L
Peña, B
Lafuente, P
Sancho, J
Michiels, W
Hidalgo, G
Martínez-Nuñez, MF
[J]. ANTEC '99: PLASTICS BRIDGING THE MILLENNIA, CONFERENCE PROCEEDINGS, VOLS I-III: VOL I: PROCESSING; VOL II: MATERIALS; VOL III: SPECIAL AREAS;, 1999, : 2242 - 2246
[5] A MOF-supported chromium catalyst for ethylene polymerization through post-synthetic modification
Liu, Bing
Jie, Suyun
Bu, Zhiyang
Li, Bo-Geng
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2014, 387 : 63 - 68
[6] A Reusable MOF-Supported Single-Site Zinc(II) Catalyst for Efficient Intramolecular Hydroamination of o-Alkynylanilines
Li, Beibei
Ju, Zhanfeng
Zhou, Mi
Su, Kongzhao
Yuan, Daqiang
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (23) : 7687 - 7691
[7] Facile one-pot synthesis of MOF supported gold pseudo-single-atom catalysts for hydrogenation reactions
Wang, Zumin
Gu, Lin
Song, Li
Wang, Hao
Yu, Ranbo
[J]. MATERIALS CHEMISTRY FRONTIERS, 2018, 2 (05) : 1024 - 1030
[8] Metal-organic framework supported single-site nickel catalysts for butene dimerization
Zheng, Jian
Loebbert, Laura
Chheda, Saumil
Khetrapal, Navneet
Schmid, Julian
Gaggioli, Carlo Alberto
Yeh, Benjamin
Bermejo-Deval, Ricardo
Motkuri, Radha Kishan
Balasubramanian, Mahalingam
Fulton, John L.
Gutierrez, Oliver Y.
Siepmann, J. Ilja
Neurock, Matthew
Gagliardi, Laura
Lercher, Johannes A.
[J]. JOURNAL OF CATALYSIS, 2022, 413 : 176 - 183
[9] Enhanced one-pot selective conversion of cellulose to ethylene glycol over NaZSM-5 supported metal catalysts
Sreekantan, Sreejith
Kirali, Arun Arunima
Marimuthu, Banu
[J]. NEW JOURNAL OF CHEMISTRY, 2021, 45 (41) : 19244 - 19254
[10] Toward single-site, immobilized molecular catalysts: Site-isolated Ti ethylene polymerization catalysts supported on porous silica
McKittrick, MW
Jones, CW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (10) : 3052 - 3053

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