N-substituted-N′-(2′,3′,4′,6′-tetra-O-acetyl)-β-D-glucopyranosyl thiocarbamides and thiosemicarbazides

被引:0
|
作者
Li, M [1 ]
Wen, LR
Jing, SX
Zhang, YB
Yang, HZ
Zhang, SS
机构
[1] Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China
[2] Qingdao Inst Chem Technol, Dept Appl Chem, Qingdao 266042, Peoples R China
[3] Lanzhou Univ, Natl Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
关键词
thiocarbamides; thiosemicarbazides; beta-D-glucopymnosyl isothiocynate; synthesis;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reaction of 2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl isothiocynate (I) with amyl hydrazine(II), 2-amino-5-alkyl/aryl-1,3,4-thiadiazoles (III), 3-alkyl/aryl-4-amino-5-mercapto-1, 2, 4-triazoles (IV) or O,O-dialkyl (thio)phosphorohydrazidates (V, VI) Wished twelve new products, which structures were assigned as 1a similar to 1c, 2d similar to 2e, 3f similar to 3i, 4j similar to 4k and 5I respectively (all with beta-configuration) on the basis of EA and spectral data.
引用
收藏
页码:1137 / 1141
页数:5
相关论文
共 50 条
  • [2] 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl azide
    Temelkoff, DP
    Norris, P
    Zeller, M
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : O1975 - O1976
  • [3] 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl azide
    Dedola, Simone
    Nepogodiev, Sergey A.
    Hughes, David L.
    Field, Robert A.
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2008, 64 : O445 - O446
  • [4] N1,N1-Diethyl-N2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)acetamidine
    Diánez, MJ
    Estrada, MD
    López-Castro, A
    Pérez-Garrido, S
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2001, 57 : 1297 - 1298
  • [5] N-glycoside neoglycotrimers from 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl azide
    Temelkoff, David P.
    Zeller, Matthias
    Norris, Peter
    [J]. CARBOHYDRATE RESEARCH, 2006, 341 (09) : 1081 - 1090
  • [6] Reaction of N-alkylisatins with 4-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)thiosemicarbazide
    Nguyen Dinh Thanh
    Nguyen Thi Kim Giang
    [J]. JOURNAL OF CHEMISTRY, 2013, 2013
  • [7] Synthesis and antibacterial and antifungal activities of N-(tetra-O-acetyl-β-d-glucopyranosyl)thiosemicarbazones of substituted 4-formylsydnones
    Nguyen Dinh Thanh
    Hoang Thanh Duc
    Vu Thi Duyen
    Phan Manh Tuong
    Nguyen Van Quoc
    [J]. Chemistry Central Journal, 9
  • [8] Synthesis of novel 1-arylsulfonyl-4-(1′-n-2′,3′,4′,6′-tetra-acetyl-O-β-glucopyranosyl)thiosemicarbazides
    Li, YX
    Li, ZM
    Zhao, WG
    Dong, WL
    Wang, SH
    [J]. CHINESE CHEMICAL LETTERS, 2006, 17 (02) : 153 - 155
  • [9] O-Ethyl and O-methyl N-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-thiocarbamate
    Zhang, SS
    Wang, ZW
    Li, M
    Jiao, K
    Razak, IA
    Raj, SSS
    Fun, HK
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2001, 57 (05) : 566 - 568
  • [10] 4-N-acetylamino-5-[N-acetyl-N-(tetra-O-acetyl-β-D-glucopyranosyl)amino]-1,3-dimethyluracil
    Rodrigo, AS
    Montiel, MN
    Cobo, J
    Low, JN
    Glidewell, C
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O969 - O971