Nonflammable electrolyte for safer non-aqueous sodium batteries

被引：65
|
作者：
Feng, Jinkui [1 ]
An, Yongling [1 ]
Ci, Lijie [1 ]
Xiong, Shenglin [2 ]
机构：
[1] Shandong Univ, Sch Mat Sci & Engn, Key Lab Liquid Solid Struct Evolut & Proc Mat, Minist Educ, Jinan 250061, Peoples R China
[2] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2015年 / 3卷 / 28期
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
LITHIUM-ION BATTERIES; NON-FLAMMABLE ELECTROLYTE; INSERTION; SOLVENT; REACTIVITY; MECHANISMS; NANOWIRES; PHOSPHATE; STORAGE; ETHER;
D O I：
10.1039/c5ta03548a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Sodium batteries are now considered as promising low-cost alternatives for lithium batteries. However, safety problems such as fire and explosion during abuse-testing conditions hinder the development of room temperature sodium batteries. To address these issues, here we propose a nonflammable electrolyte system for sodium batteries. By introducing a high-efficiency flame-retarding additive, the carbonate based electrolyte becomes flame inhibiting. Moreover, the additive can improve the cyclability of both the acetylene black (AB) anode and the Na0.44MnO2 cathode.
引用
收藏
页码：14539 / 14544
页数：6
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