Mixing Properties of Binary Liquid Mixtures of Cyclopentane with Branched Alcohols at Different Temperatures

被引:4
|
作者
Kumar, Harsh [1 ]
Chadha, Chanda [1 ]
机构
[1] Dr BR Ambedkar Natl Inst Technol, Dept Chem, Jalandhar 144011, Punjab, India
关键词
EXCESS MOLAR VOLUMES; 298.15; K; MOLECULAR-INTERACTIONS; ALIPHATIC-ALCOHOLS; REFRACTIVE-INDEX; HEAT-CAPACITIES; (1)+1-ALKANOL 2; DENSITIES; SOUND; CYCLOHEXANE;
D O I
10.1246/bcsj.20120126
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Densities, rho, and speeds of sound, u, of cyclopentane with 2-methyl-1-propanol, 3-methyl-1-butanol, and 2-methyl-2-butanol binary liquid mixtures have been measured over the whole composition range at atmospheric pressure at temperatures: 288.15, 298.15, and 308.15 K. Excess molar volumes V-m(E), isentropic compressibility K-S, and their excess counterpart excess isentropic compressibility K-S,m(E) have been calculated from experimental densities and speeds of sound. Apparent molar volume, V-phi,V-i partial molar volume, V-i, and apparent molar compressibilities have been calculated from the experimental density and speeds of measurements.
引用
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页码:1145 / 1154
页数:10
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