Aza-pinacol rearrangement: acid-catalyzed rearrangement of aziridines to imines

被引：42

作者：

Sugihara, Y ^{[1
]}

Iimura, S ^{[1
]}

Nakayama, J ^{[1
]}

机构：

[1] Saitama Univ, Dept Chem, Fac Sci, Saitama 3388570, Japan

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 02期

关键词：

D O I：

10.1039/b109445a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of di-, tri-, and tetra-substituted N-tosylaziridines [N-(toluene-p-sulfonyl) aziridines] 1, prepared by aziridination of the corresponding alkenes with N-[(tolyl-p-sulfonyl) imino] phenyliodinane (TsN = IPh), was found to undergo a BF3-catalyzed rearrangement (aza-pinacol rearrangement) under mild conditions to give the corresponding N- tosylimines 2 generally in satisfactory yields.

引用

页码：134 / 135

页数：2

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