Formation of a vinyliminium palladium complex by C-C coupling in vinylcarbene palladium aryl complexes

被引：41

作者：

Albéniz, AC

Espinet, P

Pérez-Mateo, A

Nova, A

Ujaque, G

机构：

[1] Univ Valladolid, Fac Ciencias, E-47005 Valladolid, Spain

[2] Univ Autonoma Barcelona, Unitat Quim Fis, E-08193 Barcelona, Spain

来源：

ORGANOMETALLICS | 2006年 / 25卷 / 05期

关键词：

D O I：

10.1021/om051028s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pentafluorophenyl palladium complexes 3 and 5 bearing a vinylcarbene ligand slowly decompose on heating by migratory insertion to give Pd(O) and the vinyliminium salts (Et2N=C(C6F5)CH=CHPh)X (X = Br, BF4). However, the presence of triphenylphosphine in complex 4 stabilizes 7, a compound with a C=C Pd-bound vinyliminium moiety, where there is a strong preference for the C=C versus the C=N coordination.

引用

页码：1293 / 1297

页数：5

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