Synthesis of N,N-diallylanilines by the reaction of anilines and allyl bromide in the presence of Mg-Al hydrotalcites at ambient temperature

被引：1

作者：

Shetty, Mohan R. ^{[1
]}

Kshirsagar, Siddheshwar W. ^{[1
]}

Lanka, Srikanth V. ^{[1
]}

Samant, Shriniwas D. ^{[1
]}

机构：

[1] Inst Chem Technol, Dept Chem, Bombay 400019, Maharashtra, India

来源：

GREEN CHEMISTRY LETTERS AND REVIEWS | 2012年 / 5卷 / 03期

关键词：

Mg-Al hydrotalcites; primary amines; diallylation of anilines; N-ALKYLATION; ALCOHOLS; DERIVATIVES; AMINOMERCURATION; CONVERSION; AMINATION; ROUTE;

D O I：

10.1080/17518253.2011.624127

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Anilines react with two equivalents of allyl bromide in aqueous ethanol in the presence of Mg-Al hydrotalcites (Mg/Al = 5, 3, 2) at room temperature to give N,N-diallylanilines in good yield. Hydrotalcites (HTs) are mild and efficient catalysts, which can be easily recovered and reused. In this project, efforts are made to check the activity of the calcined and uncalcined HTs. Also, the methodology can be extended for the synthesis of various N,N-diallylanilines. [GRAPHICS] .

引用

页码：291 / 301

页数：11

共 20 条

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