Synthesis and Characterization of Ferrocenyl Carboxilic Surface-Functionalized Resorcinaren-PAMAM Dendrimers

被引：3

作者：

Cortez-Maya, Sandra ^{[1
]}

Klimova, Elena ^{[1
]}

Puente Lee, R. I. ^{[1
]}

Borja-Miranda, Andres ^{[2
]}

Martinez-Garcia, Marcos ^{[2
]}

机构：

[1] Univ Nacl Autonoma Mexico, Fac Quim, Mexico City 04510, DF, Mexico

[2] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico

来源：

CURRENT ORGANIC CHEMISTRY | 2015年 / 19卷 / 19期

关键词：

Ferrocene; metallodendrimers; resorcinaren-PAMAM-dendrimers;

D O I：

10.2174/1385272819666150604000213

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A method for the synthesis of new metallodendrimers containing ferrocenyl carboxylic surface-functionalized resorcinaren-PAMAM dendrimers is reported. Dendrimers (G1.0 and G2.0) have been functionalized by covalent bond formation between the amine primary terminals and ferrocenecarboxylic acid by amide bond formation. The molecular structure of the resorcinaren-PAMAM dendrimers and metallodendrimers was characterized by 1H, 13C NMR spectroscopy and by elemental analysis. The molecular weights of the compounds were confirmed by MALDI-TOF experiments. Transmission electron microscopy (TEM) images showed the presence of metallodendrimers nanoparticles with average size of 27-30 nm with the shapes of the molecules being spherical.

引用

页码：1954 / 1960

页数：7

共 50 条

[1] Cytotoxicity and in vivo plasma kinetic behavior of surface-functionalized PAMAM dendrimers
Diaz, Carola
Benitez, Carolina
Vidal, Felipe
Barraza, Luis F.
Jimenez, Veronica A.
Guzman, Leonardo
Fuentealba, Jorge
Yevenes, Gonzalo E.
Alderete, Joel B.
NANOMEDICINE-NANOTECHNOLOGY BIOLOGY AND MEDICINE, 2018, 14 (07) : 2227 - 2234
[2] Synthesis of 5-aryl-1,4-benzodiazepine derivatives attached in resorcinaren-PAMAM dendrimers and their anti-cancer activity
Cortez-Maya, Sandra
Hernandez-Ortega, Simon
Ramirez-Apan, Teresa
Lijanova, Irina V.
Martinez-Garcia, Marcos
BIOORGANIC & MEDICINAL CHEMISTRY, 2012, 20 (01) : 415 - 421
[3] Synthesis and characterization of polyamidoamine dendrimers surface-functionalized with bromotricarbonylpyridyliminerhenium(I) units
Zhao, Xinxin
Yan, Yaw-Kai
Chu, Chit-Kay
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (26) : 5540 - 5546
[4] Electrochemical and adsorption properties of PAMAM dendrimers surface-functionalized with polypyridyl cobalt complexes
Takada, K
Storrier, GD
Goldsmith, JI
Abruña, HD
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (12): : 2404 - 2411
[5] Synthesis, characterization, electrochemistry, and EQCM studies of polyamidoamine dendrimers surface-functionalized with polypyridyl metal complexes
Cornell Univ, Ithaca, United States
Langmuir, 3 (872-884):
[6] Synthesis, characterization, electrochemistry, and EQCM studies of polyamidoamine dendrimers surface-functionalized with polypyridyl metal complexes
Storrier, GD
Takada, K
Abruña, HD
LANGMUIR, 1999, 15 (03) : 872 - 884
[7] Synthesis and characterization of surface-functionalized mesoporous graphene nanohybrid
Suchhanda. S. Swain
Lakshmi Unnikrishnan
Smita Mohanty
Sanjay K. Nayak
Applied Nanoscience, 2019, 9 : 1531 - 1552
[8] Synthesis and characterization of surface-functionalized mesoporous graphene nanohybrid
Swain, Suchhanda. S.
Unnikrishnan, Lakshmi
Mohanty, Smita
Nayak, Sanjay K.
APPLIED NANOSCIENCE, 2019, 9 (07) : 1531 - 1552
[9] Comprehensive characterization of surface-functionalized poly (amidoamine) dendrimers with acetamide, hydroxyl, and carboxyl groups
Shi, XY
Lesniak, W
Islam, MT
Muñiz, MC
Balogh, LP
Baker, JR
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2006, 272 (1-2) : 139 - 150
[10] Convergent synthesis of PAMAM-like dendrimers from azide-functionalized PAMAM
Lee, Jae Wook
Kim, Jung Hwan
Kim, Byung-Ku
Kim, Ji Hyeon
Shin, Won Suk
Jin, Sung-Ho
Kim, Myunghak
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2006, 27 (11) : 1795 - 1800

← 1 2 3 4 5 →