Long-range solid-state ordering and high geometric distortions induced in phthalocyanines by small fluoroalkyl groups

被引：14

作者：

Gorun, Sergiu M. ^{[1
]}

Rathke, Jerome W. ^{[2
]}

Chen, Michael J. ^{[2
]}

机构：

[1] New Jersey Inst Technol, Dept Chem & Environm Sci, Newark, NJ 07102 USA

[2] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA

来源：

DALTON TRANSACTIONS | 2009年 / 07期

关键词：

RAY CRYSTAL-STRUCTURE; RING-SUBSTITUTED PHTHALOCYANINES; X-RAY; METAL-FREE; PERFLUOROPHTHALOCYANINE; COMPLEXES; FLUORINE; OXYGEN; ATOM;

D O I：

10.1039/b821000b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electron-withdrawing alpha-CF3 groups sterically induce severe geometric distortions and long-range solid-state ordering in protio and catalytically active mu-oxo iron phthalocyanine.

引用

页码：1095 / 1097

页数：3

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