Multifunctional surface-modified ultrathin graphene flakes for thermal and electrochemical energy storage application

被引:2
|
作者
Padya, Balaji [1 ,2 ]
Ravikiran, N. [1 ]
Kali, Ravi [1 ]
Narasaiah, N. [2 ]
Jain, P. K. [1 ]
Rao, T. N. [1 ]
机构
[1] Int Adv Res Ctr Powder Met & New Mat ARCI, Hyderabad 500005, India
[2] Natl Inst Technol NIT, Dept Met & Mat Engn, Warangal 506004, Andhra Pradesh, India
关键词
Ultrathin graphene nanoflakes; Solution-phase exfoliation; Energy storage; Specific capacitance; Thermal conductivity; CONDUCTIVITY;
D O I
10.1016/j.matpr.2019.03.234
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This paper presents the preparation of ultrathin graphene nanoflakes (UGF) from microwave-irradiated expanded graphite, and delaminated via solution-phase exfoliation for thermal and electrochemical energy storage application. The surface of the UGF were modified with a carbon rich layer (UGF-C) to minimize restacking and prone to oxidizer-etching to create pores to support electrolyte ion transport. UGF-C exhibited specific capacitance of 83F/g at current density of 0.25 A/g with 97% capacitance retention for 1000 cycles. Also, UGF incorporated xylitol based phase change materials enhanced thermal conductivity by 40.1%. (C) 2018 Elsevier Ltd.
引用
收藏
页码:52 / 57
页数:6
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