Multifunctional surface-modified ultrathin graphene flakes for thermal and electrochemical energy storage application
被引:2
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作者:
Padya, Balaji
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Int Adv Res Ctr Powder Met & New Mat ARCI, Hyderabad 500005, India
Natl Inst Technol NIT, Dept Met & Mat Engn, Warangal 506004, Andhra Pradesh, IndiaInt Adv Res Ctr Powder Met & New Mat ARCI, Hyderabad 500005, India
Padya, Balaji
[1
,2
]
Ravikiran, N.
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Int Adv Res Ctr Powder Met & New Mat ARCI, Hyderabad 500005, IndiaInt Adv Res Ctr Powder Met & New Mat ARCI, Hyderabad 500005, India
Ravikiran, N.
[1
]
Kali, Ravi
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Int Adv Res Ctr Powder Met & New Mat ARCI, Hyderabad 500005, IndiaInt Adv Res Ctr Powder Met & New Mat ARCI, Hyderabad 500005, India
Kali, Ravi
[1
]
Narasaiah, N.
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Natl Inst Technol NIT, Dept Met & Mat Engn, Warangal 506004, Andhra Pradesh, IndiaInt Adv Res Ctr Powder Met & New Mat ARCI, Hyderabad 500005, India
Narasaiah, N.
[2
]
Jain, P. K.
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Int Adv Res Ctr Powder Met & New Mat ARCI, Hyderabad 500005, IndiaInt Adv Res Ctr Powder Met & New Mat ARCI, Hyderabad 500005, India
Jain, P. K.
[1
]
Rao, T. N.
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Int Adv Res Ctr Powder Met & New Mat ARCI, Hyderabad 500005, IndiaInt Adv Res Ctr Powder Met & New Mat ARCI, Hyderabad 500005, India
Rao, T. N.
[1
]
机构:
[1] Int Adv Res Ctr Powder Met & New Mat ARCI, Hyderabad 500005, India
[2] Natl Inst Technol NIT, Dept Met & Mat Engn, Warangal 506004, Andhra Pradesh, India
Ultrathin graphene nanoflakes;
Solution-phase exfoliation;
Energy storage;
Specific capacitance;
Thermal conductivity;
CONDUCTIVITY;
D O I:
10.1016/j.matpr.2019.03.234
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
This paper presents the preparation of ultrathin graphene nanoflakes (UGF) from microwave-irradiated expanded graphite, and delaminated via solution-phase exfoliation for thermal and electrochemical energy storage application. The surface of the UGF were modified with a carbon rich layer (UGF-C) to minimize restacking and prone to oxidizer-etching to create pores to support electrolyte ion transport. UGF-C exhibited specific capacitance of 83F/g at current density of 0.25 A/g with 97% capacitance retention for 1000 cycles. Also, UGF incorporated xylitol based phase change materials enhanced thermal conductivity by 40.1%. (C) 2018 Elsevier Ltd.