Ruthenium-catalyzed ortho-C-H halogenations of benzamides

被引：119
|
作者：
Wang, Lianhui [1 ]
Ackermann, Lutz [1 ]
机构：
[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 09期
基金：
欧洲研究理事会;
关键词：
CROSS-COUPLING REACTIONS; BOND FUNCTIONALIZATION; ARENES; IODINATION; ACTIVATION; VERSATILE; HALIDES; OXYGENATIONS; REACTIVITY; REAGENTS;
D O I：
10.1039/c3cc47852a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[Ru-3(CO)(12)] and AgO2C(1-Ad) enabled the first ruthenium-catalyzed intermolecular halogenations of arenes via C-H activation. Thereby, brominations and iodinations of electron-rich and electron-deficient benzamides were achieved in a highly selective fashion.
引用
收藏
页码：1083 / 1085
页数：3
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